Isolation of the first gallium hydrosulphido complex and its facile conversion to a Ga4S4cubane: X-ray structures of [(But)2Ga(µ-SH)]2and [(ButGaS]4
- 1 January 1991
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 18,p. 1315-1317
- https://doi.org/10.1039/c39910001315
Abstract
The reaction of (But)3Ga with an excess of H2S in pentane at ambient temperature results in the formation of the hydrosulphido bridged dimer [(But)2Ga(µ-SH)]2, 1, which upon mild thermolysis is converted to the cubic tetramer [(But)GaS]42. Compounds 1 and 2 have been characterized by IR, NMR and mass spectroscopy and their molecular structures have been determined by X-ray crystallography.Keywords
This publication has 16 references indexed in Scilit:
- Factors affecting aluminum-carbon bond reactivity of tetradentate Schiff-base organoaluminum complexesInorganic Chemistry, 1986
- Darstellung und eigenschaften von diphenylalkylthio- und diphenylarylthio-gallanen. Kristallstruktur von diphenylethylthiogallanJournal of Organometallic Chemistry, 1984
- Crystal structures of tris(diethyldithiorcarbamato)-gallium(III) and indium(III)J. Chem. Soc., Dalton Trans., 1976
- Preparation of organogallium compounds from organolithium reagents and gallium chloride. Infrared, magnetic resonance, and mass spectral studies of alkylgallium compoundsInorganic Chemistry, 1975
- Insertion reactions of diethylaluminum derivatives : X. Synthesis and properties of ethylaluminum sulfide, the initial product in the reaction of triethylaluminum with hydrogen sulfideJournal of Organometallic Chemistry, 1975
- Synthesis and some properties of bis(dimethylaluminium) sulphideJournal of Organometallic Chemistry, 1974
- Reactions of Carbonylmetal Hydrides with Aziridine and Propylene Sulfide (2‐Methylthiirane)Angewandte Chemie International Edition in English, 1973
- Chelate von β‐Diketonderivaten, VIII. Über Metallchelate des Monothiodibenzoylmethans und ihre IR‐Absorption im CarbonylbereichZeitschrift für anorganische und allgemeine Chemie, 1967
- The Structure of the Cyclic Tetramer of Dimethylgallium Hydroxide1Journal of the American Chemical Society, 1959
- Polymeric Dimethylgallium Hydroxide1 and its CondensationJournal of the American Chemical Society, 1954