Flash vacuum pyrolysis of anthracenic Diels–Alder adducts, a convenient source of methanethial and methanethial S-oxide
- 1 February 1987
- journal article
- Published by Canadian Science Publishing in Canadian Journal of Chemistry
- Vol. 65 (2) , 290-291
- https://doi.org/10.1139/v87-047
Abstract
The flash vacuum pyrolysis of Diels–Alder adducts of anthracene constitutes a rapid and selective route to methanethial 1 and methanethial S-oxide 2, as analyzed in the gas phase by photoelectron spectroscopy. Low temperature infrared and nuclear magnetic resonance (1H, 13C) spectra are also reported for sulfine 2.Keywords
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