Reactions of dicyanodi-[1,2-bis(diphenylphosphino)ethane]cobalt(II) with oxygen and alkyl halides
- 1 January 1970
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society D: Chemical Communications
- No. 10,p. 598a
- https://doi.org/10.1039/c2970000598a
Abstract
The reactions of [Co(CN)2(Ph2P·CH2·CH2·PPh2)2] with EtX and XCH2·CH2X (X = Cl, Br, I) are reported and compared with those given by the pentacyanocobaltate(II) ion: the reaction with ClCH2·CH2Cl in the presence of oxygen leads to carbon dioxide.Keywords
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