The onset of transient convective instability

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Abstract
The stability of a horizontal fluid layer when the thermal (or concentration) gradient is not uniform is examined by means of linear stability analysis. Both buoyancy and surface-tension effects are considered, and the analogous problem for a porous medium is also treated. Attention is focused on the situation where the critical Rayleigh number (or Marangoni number) is less than that for a linear thermal gradient, and the convection is not (in general) maintained. The case of constant-flux boundary conditions is examined because then a simple application of the Galerkin method gives useful results and general basic temperature profiles are readily treated. Numerical results are obtained for special cases, and some general conclusions about the destabilizing effects, with respect to disturbances of infinitely long wavelength, of various basic temperature profiles are presented. If the basic temperature gradient (considered positive, for a fluid which expands on heating, if the temperature decreases upwards) is nowhere negative, then the profile which leads to the smallest critical Rayleigh (or Marangoni) number is one in which the temperature changes stepwise (at the level at which the velocity, if motion were to occur, would be vertical) but is otherwise uniform. If, as well as being non-negative, the temperature gradient is a monotonic function of the depth, then the most unstable temperature profile is one for which the temperature gradient is a step function of the depth.