Molecular complexes. Part 15.—H Nuclear magnetic resonance T1studies of solvation and complexation in the C6H6+ CDCl3+ C6H12system
- 1 January 1978
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Faraday Transactions 2: Molecular and Chemical Physics
- Vol. 74, 1330-1341
- https://doi.org/10.1039/f29787401330
Abstract
1 H n.m.r. studies of the interaction between chloroform-d and benzene in the presence of cyclohexane provide T1 data which are used to elucidate the mechanism of the interaction. It is proposed that benzene is preferentially attracted to [2H1]chloroform “solvation shells” in which short lived bimolecular complexes are formed. The data are interpreted on this basis to show that the shell contains ≈ 12 molecules of benzene.Keywords
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