A thermochemical cycle for the heat of complexing of Na+ and K+ cations with cryptand 222 in water and methanol
- 1 January 1977
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 23,p. 893-894
- https://doi.org/10.1039/c39770000893
Abstract
Measurements of the enthalpy of transfer of cryptand 222 (I) and of the Na+ and K+ cryptates have been combined with heats of complex formation in water to yield by a thermochemical cycle the heats of complex formation in methanol.Keywords
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