Regioselective Synthesis of Alkenyl Sulfides from Alkenyl Triflates Using Palladium(0) as Catalyst

1 January 1994

journal article
letter
Published by Georg Thieme Verlag KG in Synlett

Vol. 1994 (07) , 561-562
https://doi.org/10.1055/s-1994-22930

Abstract

Secondary alkenyl triflates 2, easily obtained from the corresponding ketones 1, react with lithium thiolates in the presence of Pd(PPh₃)₄ to form secondary alkenyl sulfides 3 regioselectively (but not fully stereospecifically) in good to excellent yields.

Keywords

ALKENYL SULFIDES
ALKENYL TRIFLATES
REGIOSELECTIVE
CORRESPONDING KETONES
FORM SECONDARY
EASILY OBTAINED
LITHIUM THIOLATES

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