Nitroalkenylferrocene. III. Condensation Reaction of Acetylferrocene Using Lewis Acid and Cyclic Amine
- 1 November 1969
- journal article
- Published by Oxford University Press (OUP) in Bulletin of the Chemical Society of Japan
- Vol. 42 (11) , 3267-3269
- https://doi.org/10.1246/bcsj.42.3267
Abstract
Acetylferrocene reacted with nitromethane and morpholine in the presence of titanium(IV) chloride to give a Mannich base, 2-ferrocenyl-2-morpholino-1-nitropropane (7), whose sodium salt (8) was then converted to 2-ferrocenyl-1-nitropropene (9) by acidifying it with hydrochloric acid. In the presence of aluminum chloride in place of titanium (IV) chloride, acetylferrocene as well as 1,1′-diacetylferrocene dimerized to form α,β-unsaturated ketone, (10) or (11).This publication has 6 references indexed in Scilit:
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