Organic fluorine compounds. Part XL. Further reactions of diethyl fluoro-oxaloacetate with aldehydes
- 1 January 1968
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society C: Organic
- p. 1232-1235
- https://doi.org/10.1039/j39680001232
Abstract
The scope of the synthesis of α-fluoro-unsaturated acids from aliphatic and aromatic aldehydes and diethyl fluoro-oxaloacetate has been studied. α-Formyl derivatives of ketones and esters react in their aldehydic forms. 2-Fluoro-3-(2-thienyl)acrylic acid could be nitrated, probably in the 5-position of the thiophen ring. 2-Fluoro-3-(1-naphthyl)acrylic acid cyclized to 2-fluoro-4,5-benzinden-1-one (VIII).Keywords
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