Manganese(II) based oxidation of alkanes: generation of a high valent binuclear catalyst in situ
- 1 January 1994
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 16,p. 1885-1886
- https://doi.org/10.1039/c39940001885
Abstract
The efficiently Mn2+-catalysed oxidation of saturated hydrocarbons by alkylhydroperoxides or iodosylbenzene in the presence of 2,2′-bipyridine in acetonitrile follows the following pathway: Mn2++ bipy →[Mn(bipy)3]2+→[Mn2O2(bipy)4]3+, the latter being identified as the catalytic species; it affords cyclohexanol and cyclohexanone in equal amounts and the remarkable robustness of the active complex, under oxidative conditions, is noted.Keywords
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