Zusammensetzung von Rohsulfan, Nachweis der Sulfane H2S9 bis H2S35 Composition of Crude Sulfane Oil, Identification of the Sulfanes H2S9 to H2S35
Open Access
- 1 February 1985
- journal article
- Published by Walter de Gruyter GmbH in Zeitschrift für Naturforschung B
- Vol. 40 (2) , 263-272
- https://doi.org/10.1515/znb-1985-0220
Abstract
In benzene solution the position of the 1H NMR signals of sulfanes, H2Sn, strongly depends on the sulfur chain length and on the sulfane concentration. Under proper conditions all sulfanes in a mixture are characterized by well-resolved NMR signals showing a downfield shift with increasing length of the sulfur chain. The shift differences between the higher homologues ( n > 8 ) remain nearly constant, thus allowing the assignment of the signals up to H2S35 and the determination of the complete sulfane distribution in crude oils. In sulfane mixtures without solvent as well as in CS2 and CCl4 solutions, however, H2S8 shows the largest downfield shift. The signals of the higher sulfanes overlap in a narrow range at slightly higher field and cannot be characterized except for the CCl4 solution where an assignment up to H2S11 is possible. The chemical shifts are interpreted in terms of inter- and intramolecular hydrogen bondings. The upfield shift caused by benzene is attributed to the formation of H2Sn · benzene complexes.Keywords
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