Seasonal Variations in Aerosol Composition and Acidity at Shenandoah and Great Smoky Mountains National Parks

Abstract
The concentration of elements Na through Pb, select ions, and organic carbon from fine (s (moles of hydrogen associated with sulfur) to S (moles of sulfur) ratio of approximately 4. This suggests the average sulfate particle during the summer has a molar coon slightly more acidic than ammonium bisulfate (NH4HSO4) which has a molar hydrogen to sulfur ratio of 5. Winter Hs to S ratios, however, are approximately 8, suggesting the aerosol is on average fully neutralized ammonium sulfate [(NH4)2SO4].

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