Toward Creation of a Universal NMR Database for the Stereochemical Assignment of Acyclic Compounds: The Case of Two Contiguous Propionate Units
- 1 December 1999
- journal article
- letter
- Published by American Chemical Society (ACS) in Organic Letters
- Vol. 1 (13) , 2177-2180
- https://doi.org/10.1021/ol9903786
Abstract
Using triol 1 as a representative example of natural products containing two contiguous propionate units, 13C and 1H NMR databases for the stereochemical assignment of acyclic compounds have been created. Chemical shift increments due to the presence of additional functional groups as well as solvent effects are discussed.Keywords
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