EXAFS Studies of the Behavior of Rh6(CO)16 Supported on γ-Al2O3 Surface
- 1 February 1986
- journal article
- research article
- Published by Oxford University Press (OUP) in Bulletin of the Chemical Society of Japan
- Vol. 59 (2) , 647-648
- https://doi.org/10.1246/bcsj.59.647
Abstract
The structural change of Rh6(CO)16 supported on γ-Al2O3 surface during a decarbonylation–recarbonylation cycle was studied by means of EXAFS (extended X-ray absorption fine structure) spectroscopy. Rh6(CO)16 cluster framework was found to be decomposed into Rh(CO)2(OAl(Remark: Graphics omitted.))2 after the reaction with a mixture of O2 and H2O, and reversely regenerated by the subsequent treatment with a mixture of CO and H2O.Keywords
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