On the adsorption of a polymer chain at a boundary
- 1 January 1972
- journal article
- research article
- Published by Wiley in Journal of Polymer Science Part C: Polymer Symposia
- Vol. 39 (1) , 305-309
- https://doi.org/10.1002/polc.5070390127
Abstract
On the basis of a simple lattice model, the adsorption of a polymer chain on a surface is discussed, taking excluded volume effects (intrachain interactions) into account. Configurations of finite chains of n elements (self‐avoiding walks) are enumerated exactly for n ≤ 13 on the simple cubic lattice. Some predictions concerning the asymptotic behavior of long chains are derived from these data by using extrapolation methods previously devised by Domb and Sykes for bulk properties.Keywords
This publication has 4 references indexed in Scilit:
- Adsorption of Flexible Macromolecules. IV. Effect of Solvent–Solute Interactions, Solute Concentration, and Molecular WeightThe Journal of Chemical Physics, 1968
- Random-Walk Model of Chain-Polymer Adsorption at a SurfaceThe Journal of Chemical Physics, 1965
- Self-Avoiding Walks on the Simple Cubic LatticeThe Journal of Chemical Physics, 1963
- The Adsorption of Flexible MacromoleculesThe Journal of Physical Chemistry, 1953