Negative Magneto-resistance Observed on an Ion-radical Salt of a TTF-based Spin-polarized Donor
- 2 December 2006
- journal article
- Published by Oxford University Press (OUP) in Chemistry Letters
- Vol. 36 (1) , 110-111
- https://doi.org/10.1246/cl.2007.110
Abstract
A novel diselena analogue of TTF-based spin-polarized donor was synthesized. An ion-radical salt of the donor electro-crystallized on an interdigitated electrode with 2 μm gap showed negative magneto-resistance below 15 K. This is the first example detecting the interaction between localized spin and conducting electron in a genuine organic system.Keywords
This publication has 22 references indexed in Scilit:
- Magnetic TTF-Based Charge-Transfer ComplexesChemical Reviews, 2004
- Molecular Paramagnetic Semiconductor: Crystal Structures and Magnetic and Conducting Properties of the Ni(dmit)2 Salts of 6-Oxoverdazyl Radical Cations (dmit = 1,3-Dithiol-2-thione-4,5-dithiolate)Inorganic Chemistry, 2003
- An Indication of Magnetic-Field-Induced Superconductivity in a Bifunctional Layered Organic Conductor, κ-(BETS)2FeBr4Journal of the American Chemical Society, 2002
- Coexistence of ferromagnetism and metallic conductivity in a molecule-based layered compoundNature, 2000
- MagnetoelectronicsScience, 1998
- Recent progress in the development of organomagnetic materials based on neutral nitroxide radicals and charge transfer complexes derived from nitroxide radicalsJournal of Materials Chemistry, 1997
- Intermolecular Ferromagnetic Interaction of 4-(1-Pyrenylmethyleneamino)-2,2,6,6-Tetra Methylpiperidin-1-OxylMolecular Crystals and Liquid Crystals, 1993
- New models for organic magnetic conductors or organic kondo and dense kondo systemsSynthetic Metals, 1991
- Magnetic interactions among unpaired electrons in charge-transfer complexes of organic donors having a neutral radicalSynthetic Metals, 1991
- Possibilities of organic ferromagnets and ferrimagnets by the use of charge-transfer (CT) complexes with radical substituents. Ab initio MO studiesChemical Physics Letters, 1990