Magnetic Interactions for the Electronic Configuration d5

15 April 1967

journal article
research article
Published by AIP Publishing in The Journal of Chemical Physics

Vol. 46 (8) , 2907-2911
https://doi.org/10.1063/1.1841153

Abstract

Applying Horie's method, the matrix elements of spin—other‐orbit interaction for configuration d⁵ have been calculated. The magnetic interaction energy has also been calculated for Mn⁺⁺ by means of perturbation theory. It is found that spin—other‐orbit interaction plays a very important role for atoms or ions with half‐filled‐shell configuration. Spin—spin interaction is also significant in certain terms.

Keywords

This publication has 9 references indexed in Scilit:

Theory of spin-orbit coupling in atoms, II. Comparison of theory with experiment
Proceedings of the Royal Society of London. Series A. Mathematical and Physical Sciences, 1963
Theory of spin-orbit coupling in atoms I. Derivation of the spin-orbit coupling constant
Proceedings of the Royal Society of London. Series A. Mathematical and Physical Sciences, 1962
Spin-spin and Spin-other-orbit Interactions
Progress of Theoretical Physics, 1953
$L (L + 1)$ Correction in the Spectra of the Iron Group
Physical Review B, 1952
The $L (L + 1)$ Correction to the Slater Formulas for the Energy Levels
Physical Review B, 1952
Spin-Spin Interaction
Physical Review B, 1951
Theory of Complex Spectra. III
Physical Review B, 1943
Theory of Complex Spectra. II
Physical Review B, 1942
Term Formulae for the Configuration $d^{5}$
Physical Review B, 1942