A Kinetic Fluorimetric Method for Determination of Microamounts of Pt(IV) with 2-2′ Dipyridylketone Hydrazone

Abstract
A kinetic method for determination of traces of Pt(IV) based on the aerobic oxidation of the hydrazone of 2-2′ dipyridylketone, in which the formation of a fluorescent product (λex = 359 nm, λem = 435 nm) takes place, is described. The reaction is followed by the measurement of the rate of appearance of the fluorescence. The proposed method suffers very few interferences.

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