Polymerization studies on allylic compounds. Part II
- 1 March 1964
- journal article
- research article
- Published by Wiley in Journal of Polymer Science Part A: General Papers
- Vol. 2 (3) , 1355-1363
- https://doi.org/10.1002/pol.1964.100020332
Abstract
The free radical polymerization of a series of compounds having the general formula magnified image in which Y was F, Cl, Br, I, NO2, and CN has been studied. The compounds were found to vary markedly in polymerizability. An explanation is advanced in which it is postulated that chain transfer involving a substituent in the allylic position of the monomers is the controlling factor in determining their polymerization behavior.Keywords
This publication has 5 references indexed in Scilit:
- Allyl polymerization. V. Effective chain transfer in the polymerization of 3-buten-2--yl acetate. Polymerization of 3-buten-2--olJournal of Polymer Science, 1959
- Allyl polymerization. IV. Effective chain transfer in polymerization of allylic monomersJournal of Polymer Science, 1956
- THE ACTION OF MINERAL ACID ON DIETHYL BIS(HYDROXYMETHYL)MALONATE1The Journal of Organic Chemistry, 1955
- Allyl Polymerization. II. Decomposition of Benzoyl Peroxide in Allyl Esters1,2Journal of the American Chemical Society, 1952
- The Polymerization of Allyl Compounds. I. Factors Governing the Acyl Peroxide-Induced Polymerization of Allyl Acetate, and the Fate of the PeroxideJournal of the American Chemical Society, 1945