The structure of bis-π-cyclopentadienyldi-iron tetracarbonyl in solution
- 1 January 1968
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in J. Chem. Soc. A
- p. 1319-1324
- https://doi.org/10.1039/j19680001319
Abstract
The infrared spectrum of [π-C5H5Fe(CO2)2] is markedly solvent dependent in the 500–700, 1700–2100, and 3500–4000 cm.–1 regions. The spectra can best be explained on the assumption that there are two bridged and one non-bridged isomer present in solutions, and that their proportions vary from solvent to solvent. These suggestions also account for the dipole moment of the compound.Keywords
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