Orthogonal Projection Approach Applied to Peak Purity Assessment
- 1 January 1996
- journal article
- research article
- Published by American Chemical Society (ACS) in Analytical Chemistry
- Vol. 68 (1) , 79-85
- https://doi.org/10.1021/ac950496g
Abstract
The orthogonal projection approach (OPA), a stepwise approach based on an orthogonalization algorithm, is proposed. The performance of OPA for the assessment of peak purity in HPLC−DAD is described and compared with that of SIMPLISMA. The occurrence of artifacts in both approaches under nonideal situations is discussed.Keywords
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