Potassium: calcium exchange in soils of the Broadbalk experiment at Rothamsted

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Abstract
Soils from Broadbalk field were used to find whether differences in K-manuring had altered K:Ca exchange relationships during 100 years cropping with wheat, by measuring cation exchange capacities and quantity/intensity (Q/I) relationships.Cation exchange capacities (CECs) were measured with and without the contribution of the soil organic matter and the following mainly non-significant trends arose during 100 years: (1) The CECs of plots given K fertilizer increased slightly when the organic contribution is included and decreased slightly when it is not. (2) The CEC of the plot given farmyard manure increased greatly when the organic contribution is included and decreased slightly when it is not. (3) The CEC of the unfertilized plot increased very slightly, whether or not the organic contribution is included.The K buffer capacity, the slope of the Q/Icurve when the soil neither gains nor loses K, was related to the K saturation of the CEC better when the organic contribution was omitted from the CEC than when it was included, suggesting that K: Ca exchange measured by the Q/Icurves occurs mainly on the non-organic part of the CEC. Two soils depleted of K had anomalously large buffer capacities, but two undepleted samples behaved similarly.Superimposing Q/Icurves by eye showed no appreciable differences between samples from different years or from different plots, even at large activity ratios. Plotting exchangeable K against I0, the activity ratio when the soil neither gains nor loses K, gave a single curve embracing all plots from all years, similar to the superimposed Q/I curves. Long–term manuring with ammonium sulphate has not affected K–Ca exchange.