Selective alkane C–C bond cleavage via prior dehydrogenation by a transition metal complex
- 1 January 1984
- journal article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 19,p. 1260-1261
- https://doi.org/10.1039/c39840001260
Abstract
1,1-Dimethylcyclopentane is dehydrogenated to form [(η4-C5H4Me2)IrL2]+[L =(p-FC6H4)3P] and then rearranged to give [(η5-C5H4Me)Ir(Me)L2]+ by [IrH2(Me2CO)2L2]+, the first case of homogeneous C–C bond cleavage starting from an alkane with a transition metal complex.Keywords
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