Yanovsky reaction of η6-arene-η5-cyclopentadienyliron cations with carbanions derived from ketones. Regiospecific attack ortho to electron withdrawing functions
- 1 January 1985
- journal article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 19,p. 1296-1297
- https://doi.org/10.1039/c39850001296
Abstract
η6-Arene-η5-cyclopentadienyliron salts containing electron withdrawing groups such as nitro, halogeno, benzoyl, cyano, and sulphonyl on the arene ring react with carbanions to give eletroneutral adducts of the Yanovsky type; these adducts give the corresponding substituted benzene on treatment with buffered cerium(IV) ammonium nitrate.Keywords
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