Electrochemical reduction of a heterodienetricarbonyliron(0) complex as a route to novel tricarbonyliron anions
- 1 January 1978
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 13,p. 552-553
- https://doi.org/10.1039/c39780000552
Abstract
Electrochemical reduction of benzylideneacetonetricarbonyliron(0)(1) affords the anionic species (2), (3), or (4); reaction of (2) or (3) with crotyl halides gives the bisallyliron(II) complex (5) and reaction of (4) with the tropylium cation gives the polyeneiron(0) complex (6).Keywords
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