Vegetable Purgatives Containing Anthracene Derivatives: Part XI. Further Work on the Aloin-like Substance ofRhamnus purshiana DC

Publisher Website
Google Scholar
Abstract
The aloin-like substance formerly referred to as Compound A1, has been resolved into four closely allied anthraquinone derivatives by paper chromatographic and countercurrent techniques. Two of these substances have been isolated in pure form and their general properties, melting point, optical rotation, RF values and ultra-violet light absorption curves are recorded. Treatment with ferric chloride yields aloe-emodin from both, and each on mild hydrolysis, produces barbaloin. The names Cascaroside A and Cascaroside B are proposed. Preliminary work on the other two components has shown that they are based on a compound similar to barbaloin but a derivative of chrysophanol instead of aloe-emodin; the name chrysaloin is suggested for this substance.

This publication has 2 references indexed in Scilit: