Synthesis of Functional Olefins Using the Wittig-Horner Reaction in Different Media
- 1 December 1999
- journal article
- research article
- Published by Taylor & Francis in Synthetic Communications
- Vol. 29 (23) , 4201-4222
- https://doi.org/10.1080/00397919908085894
Abstract
A convenient procedure for the synthesis of E-oletins bearing electron donor-acceptor groups is reported. A new diethyl N-aryl aminobenzylphosphonate (1d) was synthesized. Reactivity of Wittig-Homer reaction is compared. Expansion of the π-conjugate chain involves the reduction of N-methoxy-N-methyl amide to aldehyde by reaction with DIBAL-H.Keywords
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