The unexpectedly slow approach to thermodynamic equilibrium of the silicate anions in aqueous tetramethylammonium silicate solutions
- 1 January 1986
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 1,p. 66-67
- https://doi.org/10.1039/c39860000066
Abstract
Contrary to the widely accepted picture of the dynamics of alkaline silicate solutions, tetramethylammonium silicate solutions require many days to re-establish thermodynamic equilibrium following a perturbation, as monitored by 29Si n.m.r. spectroscopy.Keywords
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