Microemulsion networks: the onset of bicontinuity
Open Access
- 17 February 2000
- journal article
- Published by IOP Publishing in Journal of Physics: Condensed Matter
- Vol. 12 (8A) , A253-A262
- https://doi.org/10.1088/0953-8984/12/8a/332
Abstract
We predict theoretically the gradual formation of fluctuating, connected microemulsion networks from disconnected cylinders as the spontaneous curvature and the radius are varied, in agreement with recent direct measurements of these topological transitions. We discuss the role of the topological defects, the network junction and the end-cap of the disconnected cylinders, in the connectivity transition. The optimal shapes and curvature energies of the junctions and end-caps are calculated numerically and compared with analytic approximations.Keywords
This publication has 15 references indexed in Scilit:
- Topology, Phase Instabilities, and Wetting of Microemulsion NetworksPhysical Review Letters, 2000
- Direct Observation of Phase Separation in Microemulsion NetworksLangmuir, 1999
- Percolation in Nonionic Water-in-Oil−Microemulsion Systems: A Small Angle Neutron Scattering StudyLangmuir, 1998
- Ultralow interfacial tensions in water–n-alkane–surfactant systemsThe Journal of Chemical Physics, 1997
- Scaling Laws for Microemulsions Governed by Spontaneous CurvaturePhysical Review Letters, 1997
- Evidence of corresponding states in ternary microemulsions of water - alkane -Journal of Physics: Condensed Matter, 1996
- Weakly to strongly structured mixturesPhysical Review E, 1993
- Wetting in water–oil–nonionic amphiphile mixturesThe Journal of Chemical Physics, 1991
- Microemulsions: a qualitative thermodynamic approachThe Journal of Physical Chemistry, 1990
- Cylindrical microemulsions: a polymer-like phase ?Journal de Physique Lettres, 1984