Efficient Transformation of Methyl Propargyl Ethers into α,β-Unsaturated Ketones
- 1 June 1991
- journal article
- Published by Oxford University Press (OUP) in Bulletin of the Chemical Society of Japan
- Vol. 64 (6) , 2013-2015
- https://doi.org/10.1246/bcsj.64.2013
Abstract
Methyl propargyl ethers, obtained from carbonyl compounds by successive treatment with an acetylide and MeI, were easily converted to the corresponding α,β-unsaturated ketone by regioselective hydration of acetylenic moiety followed by elimination of methanol under the catalytic action of Au(III).This publication has 9 references indexed in Scilit:
- Catalytic hydration of alkynes with Zeise's dimerOrganometallics, 1990
- Alkyne addition reactions on pentaammineosmium(II): the formation of .pi.-enol and .pi.-vinyl ether complexesJournal of the American Chemical Society, 1989
- Regioselective hydration of alkynones by palladium catalysisTetrahedron Letters, 1987
- Palladium catalyzed synthesis of heterocyclesPure and Applied Chemistry, 1983
- Phenylmercuric hydroxide. A highly selective reagent for the hydration of nonconjugated terminal alkynesThe Journal of Organic Chemistry, 1982
- A rapid, simple, and mild procedure for alkylation of phenols, alcohols, amides and acidsTetrahedron, 1979
- A Synthesis of cis-JasmoneJournal of the American Chemical Society, 1964
- A New Synthesis of 1,4- and 1,5-DiketonesJournal of the American Chemical Society, 1964
- Reactions of Acetylenic Compounds Catalyzed by Sulfonated Polystyrene ResinsJournal of the American Chemical Society, 1953