Influence of Changing Atmospheric Circulation on Precipitation δ18O–Temperature Relations in Canada during the Holocene

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Abstract
Postglacial precipitation δ18O history has been reconstructed for two regions of Canada. Long-term shifts in the oxygen-isotope composition of annual precipitation (δ18Op) in southern Ontario appear to have occurred with a consistent isotope–temperature relation throughout the past 11,50014C yr. The modern isotope–temperature relation in central Canada near present boreal treeline evidently became established between 5000 and 4000 years ago, although the relation during the last glacial maximum and deglaciation may also have been similar to present. In the early Holocene, however, unusually high δ18Opapparently persisted, in spite of low temperature locally, probably associated with high zonal index. A rudimentary sensitivity analysis suggests that a small reduction in distillation of moisture in Pacific air masses traversing the western Cordillera, perhaps accompanied by a higher summer:winter precipitation ratio, could have been responsible for the observed effect. Equivalent isotope–temperature “anomalies” apparently occurred elsewhere in western North America in response to changing early-Holocene atmospheric circulation patterns, suggesting that a time-slice map of δ18Opfor North America during this period might provide a useful target for testing and validation of atmospheric general circulation model simulations using isotopic water tracers.