Synthesis and hydrolysis of 3-methyladenosine
- 1 January 1979
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 3,p. 135
- https://doi.org/10.1039/c39790000135
Abstract
Methylation of N′-benzyloxy-5-formamido-1-β-D-ribofuranosylimidazole-4-carboxamidine (1) followed by hydrogenolysis of the N′-benzyloxy group and cyclization gave the hitherto unknown 3-methyladenosine (4), which was easily hydrolysed to 3-methyladenine (6) in 0·1 N aq. HCl and to the imidazole ribosides (3) and (5) under basic conditions.This publication has 1 reference indexed in Scilit:
- Puromycin. Synthetic Studies. X. A Novel Breakdown of the Purine Ring SystemJournal of the American Chemical Society, 1955