ENDOR spectra of some semiquinone radical-anions
- 1 January 1972
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Faraday Transactions 2: Molecular and Chemical Physics
- Vol. 68, 470-475
- https://doi.org/10.1039/f29726800470
Abstract
The proton ENDOR spectra of the radical-anions of several semiquinones in alkaline ethanol solution are reported. p-Benzosemiquinone and 2,5-dimethyl-p-benzosemiquinone are converted to di-alkoxy substituted derivatives through reaction with the solvent. When this happens the e.s.r. spectra become complicated because the spectra of the primary and secondary radicals overlap: the power of ENDOR for analyzing overlapping e.s.r. spectra is illustrated.Keywords
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