Stereoselective synthesis of arylglycine derivatives using arene–manganese tricarbonyl complexes
- 1 January 1989
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 10,p. 659-661
- https://doi.org/10.1039/c39890000659
Abstract
Arene–Mn(CO)3 cations react with the Schöllkopf chiral glycine enolate equivalent (1) or (2) to give dienyl–Mn(CO)3 complexes which are converted to arylglycine methyl esters; the reaction sequence can be performed on arene–Mn(CO)3 complexes having protected amino acid substituents to give diaryl ethers having amino ester groups on both aromatic rings.Keywords
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