Electrocatalytic reduction of CO2in water on a polymeric [{Ru0(bpy)(CO)2}n](bpy = 2,2′-bipyridine) complex immobilized on carbon electrodes
- 1 January 1994
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 2,p. 189-191
- https://doi.org/10.1039/c39940000189
Abstract
The electrocatalytic reduction of CO2 on a carbon/[{Ru0(bpy)(CO)2}n](bpy = 2,2′-bipyridine) modified electrode, prepared by electrochemical reduction of [RuII(bpy)(CO)2Cl2], leads to the selective and quantitative formation of CO even in pure aqueous electrolyte; the stability of the modified cathode is improved by using a preformed polypyrrolic film functionalized with this complex.Keywords
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