Studies on a model copper mono-oxygenase system: peroxo–CuIIbinuclear intermediates in the hydroxylation of an aromatic ring
- 1 January 1984
- journal article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 14,p. 939-940
- https://doi.org/10.1039/c39840000939
Abstract
Hydrogen peroxide reacts with a CuII complex of a m-xylyl binucleating ligand with concomitant hydroxylation to give a phenoxo-bridged complex (previously found as the product of the reaction of dioxygen with the CuI analogue) whereas a newly synthesized mononuclear analogue is unreactive, thereby implicating µ-peroxo–CuII intermediates in the hydroxylation reaction.Keywords
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