Highly Electrophilic Olefin Polymerization Catalysts. Quantitative Reaction Coordinates for Fluoroarylborane/Alumoxane Methide Abstraction and Ion-Pair Reorganization in Group 4 Metallocene and “Constrained Geometry” Catalysts
- 14 February 1998
- journal article
- research article
- Published by American Chemical Society (ACS) in Journal of the American Chemical Society
- Vol. 120 (8) , 1772-1784
- https://doi.org/10.1021/ja972912f
Abstract
No abstract availableKeywords
This publication has 35 references indexed in Scilit:
- Binuclear zirconocene cations with μ-CH3-bridges in homogeneous Ziegler-Natta catalyst systemsJournal of Molecular Catalysis A: Chemical, 1996
- Reaction of (Butadiene)zirconocene with Tris(pentafluorophenyl)borane—A Novel Way of Generating Methylalumoxane‐Free Homogeneous Ziegler‐Type CatalystsAngewandte Chemie International Edition in English, 1995
- .eta.5-C5Me5TiMe3-B(C6F5)3: A true Ziegler-Natta catalyst for the syndiotactic-specific polymerization of styreneJournal of the American Chemical Society, 1995
- Effect of polarity of the medium on the stereospecific polymerization of propylene by ansa-zirconocene catalystJournal of Polymer Science Part A: Polymer Chemistry, 1994
- Synthesis of Base-Free Cationic Zirconium Methyl and Benzyl Complexes. The Crystal and Molecular Structure of {C5H3(SiMe3)2-1,3}2ZrMe(.mu.-Me)B(C6F5)3Organometallics, 1994
- Organometallic compounds of Group III. 52. Active sites for ethylene polymerization with titanium(IV) catalysts in homogeneous media: multinuclear NMR study of ion-pair equilibria and their relation to catalyst activityOrganometallics, 1993
- Novel arene complexes of titanium(IV), zirconium(IV), and hafnium(IV)Journal of the American Chemical Society, 1993
- Reactions of the neohexyl iodide complex [(.eta.5-C5H5)Re(NO)(PPh3)(ICH2CH2C(CH3)3)]+BF4- and nucleophiles: stereochemistry of carbon-iodine bond cleavage in highly accelerated SN2 reactionsOrganometallics, 1991
- Silver(I) complexes of dichloromethane and 1,2-dichloroethaneJournal of the American Chemical Society, 1990
- .pi.-Cyclopentadienyl and .pi.-indenyl compounds of titanium, zirconium, and hafnium containing .sigma.-bonded organic substituentsJournal of the American Chemical Society, 1973