A Honeycomb Network of a Paddlewheel-type Dirhodium Complex in Two Oxidation States and Pinning of the Oxidation States
- 27 December 2002
- journal article
- research article
- Published by Oxford University Press (OUP) in Chemistry Letters
- Vol. 32 (2) , 120-121
- https://doi.org/10.1246/cl.2003.120
Abstract
The reaction of a mixture of [Rh2(acam)4(H2O)2] (Hacam = acetamide) and its radical cation salt with sodium chloride in an aqueous solution gave a mixed-valent 2-D honeycomb crystal of [{Rh2(acam)4}3(μ3-Cl)2]n·4nH2O. The oxidation states of the dirhodium units are pinned at each of the crystal sites by hydrogen bonding with solvate-water molecules.This publication has 12 references indexed in Scilit:
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