Indirect Electrooxidation of Alcohols by a Double Mediatory System with [R2N+= O]/R2N-O . and [Br. or Br+]Br-Redoxes
- 1 January 1990
- journal article
- letter
- Published by Georg Thieme Verlag KG in Synlett
- Vol. 1990 (01) , 57-58
- https://doi.org/10.1055/s-1990-20988
Abstract
A double mediatory system consisting of N-oxoammonium salts and active bromine species, generated from 2,2,6,6-tetramethylpiperidine-1-oxyl derivatives and bromide ion as recyclable reagents, is useful for the selective electrooxidation of primary and secondary alcohols to aldehydes and ketones, respectively, in an aqueous-organic two-phase system.Keywords
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