New titanium imido chemistry
- 1 January 1997
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 22,p. 2127-2134
- https://doi.org/10.1039/a704194b
Abstract
A general entry point to new titanium imido chemistry is gained via the readily prepared synthons [Ti(NR)Cl2(py)3] (R = But or aryl) and their homologues, from which straightforward metathesis reactions afford a wide range of derivatives. The structures, solution dynamics and reactivity of these new compounds are reviewed.Keywords
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