Photochemical degradation of blends of polystyrene and poly(2,6 ‐dimethyl‐1,4‐phenylene oxide)

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Abstract
Blends of polystyrene and poly(2,6‐dimethyl‐1,4‐phenylene oxide) that cover the entire compositional range have been subjected to the action of singlet oxygen from microwave discharge, dye‐sensitized reaction, and photochemical oxidation. With the applied analytical technique, which consisted of infrared (IR) analysis, including ATR technique and a spectroscopic method combined with chemical analysis for hydroperoxide groups, it was not possible to detect any effect of the singlet oxygen treatment. For that reason singlet oxygen does not appear to be important to the initiation of the photooxidation of these blends. In connection with photochemical oxidation the interaction observed between the two components probably involves energy transfer from PS to PPO. This interaction results in the enhancement of reactions in PPO that lead to greater carbonyl group formation and crosslinking. Simultaneously, the probability of chain scission in the PS is lowered with increased PPO content, found by determining the changes in the molecular weights.