Reaction of fluoro-olefins with tricarbonyl(buta-1,3-diene, trimethylenemethane, or cinnamaldehyde)iron
- 1 January 1971
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society D: Chemical Communications
- No. 19,p. 1230-1231
- https://doi.org/10.1039/c29710001230
Abstract
Tetrafluoroethylene and hexafluoropropene react with Fe(CO)3(diene)(diene = buta-1,3-diene, isoprene, or cinnamaldehyde) or tricarbonyl(trimethylenemethane)-iron to form π-allylic complexes, in which the iron atom and the allyl group are linked by a fluorocarbon chain; treatment of [[graphic omitted](CO)2π-C4Me4] with trimethyl phosphite leads to a similar linking reaction.Keywords
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