Novel ruthenium(V) dioxo complexes: synthesis, characterization, and reactivity of trans-[Ru V (tmc)(O)2]ClO4(tmc = 1,4,8,11-tetramethyl-1,4,8,11-tetra-azacyclotetradecane)
- 1 January 1986
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 3,p. 229-230
- https://doi.org/10.1039/c39860000229
Abstract
trans-[RuV(tmc)(O)2]ClO4(tmc = 1,4,8,11-tetramethyl-1,4,8,11-tetra-azacyclotetradecane) has been generated by electrochemical reduction of trans-[RuVI(tmc)(O)2](ClO4)2 in acetonitrile; it is paramagnetic (µeff.= 1.98 µB) and rapidly disproportionates into trans-[RuVI(tmc)(O)2]2+ and trans-[RuIV(tmc)(O)(OH2)]2+ upon dissolution in aqueous acidic solution.Keywords
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