Novel organosulfur donors containing hydroxy functionalities: synthesis of bis[2,2-bis(hydroxymethyl)propane-1,3-diyldithio]tetrathiafulvalene and related materials †
- 1 February 2001
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Perkin Transactions 1
- No. 4,p. 407-414
- https://doi.org/10.1039/b007660k
Abstract
The synthesis of four novel organosulfur donors carrying two or more hydroxymethyl groups are described. TTF nuclei are fused to 1,4-dithiepine and/or 1,4-dithiine rings and in two cases both outer rings carry functionality capable of introducing hydrogen bonding; for the two chiral organosulfur donor molecules both racemic and enantiopure forms are prepared.Keywords
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