Silver‐ BaCe0.8Gd0.2 O 3 Composites as Cathode Materials for SOFCs Using BaCeO3‐Based Electrolytes

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Abstract
Composites of silver and ceramics have been studied as cathode materials for intermediate‐temperature solid oxide fuel cells using ‐based electrolytes. Results indicate that the electrochemical properties of these composites are quite sensitive to the composition and microstructure of the electrodes. The optimal silver content of the composites seems to fall within the range of 50 to 70 volume percent, depending on the particular microstructure of the electrode. As compared to pure silver electrodes, the composite electrodes show better adhesion to the electrolyte, higher exchange current densities, and lower cathodic overpotentials under various conditions. The observed high performance of the composite electrodes is attributed primarily to the fine‐grained microstructure and high porosity of the composites, as the phase inhibits grain growth of the silver phase in the composites.

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