Neue mixed-valence-Verbindungen mit Sb(III) und Sb(V) vom Typ (RH+)8(C1-)4SbCl6 3- SbCl6 - / New Mixed-valence Compounds with Sb(III) and Sb(V) of the Structure (RH+)8(Cl-)4SbCl6 3-SbCl6 -
Open Access
- 1 August 1979
- journal article
- Published by Walter de Gruyter GmbH in Zeitschrift für Naturforschung B
- Vol. 34 (8) , 1059-1063
- https://doi.org/10.1515/znb-1979-0804
Abstract
New mixed-valence-compounds with Sb(III) and Sb(V) of the structure (RH+)8(Cl-)4SbCl6 3-SbCl6 - with R equal CH3CH(NH2)CH3, CH3CH(NH2)CH2CH3, CH3CH2CH2NH2, and CH3CH(CH2NH2)CH3 are reported. Different methods of preparation for these compounds are described. Compounds with the structure (RH+)8(Br-)4SbCl6 3-SbCl6 - are obtained with R = CH3CH(NH2)CH2CH3 and CH3CH(NH2)CH3. All compounds are characterised, their formation is discussedKeywords
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