The orderly progression of redox behaviour of 4d- and 5d-hexacworometallate complexes
- 1 January 1985
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 21,p. 1503-1505
- https://doi.org/10.1039/c39850001503
Abstract
A comprehensive study of the redox behaviour of 4d- and 5d-hexachlorometallates (Zr to Pd and Ta to Pt, omitting only Tc) has been undertaken in methylene chloride; the successive reversible E° value for the redox couples [MCl6]z/z–1(Z = 0, –1, –2, –3) follow orderly trends which have been interpreted in terms of core-charge and inter-electronic correlation terms, and the redox behaviour of the hexachlorometallates is compared to that of the hexafluorometallates.Keywords
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