Synthesis of µ-carbene complexes of rhodium from substituted diazirines
- 1 January 1987
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 17,p. 1285-1287
- https://doi.org/10.1039/c39870001285
Abstract
The reaction of aryl(methoxy)diazirines with [(η5-C5Me5)2Rh2(µ-CO)2] yields [(η5-C5Me5)2Rh2(CO)2{µ-C(OMe)Ar}] in near quantitative yield; the complex with Ar = 4-FC6H4 has been characterised by X-ray diffraction.Keywords
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