Keten intermediates in the uncatalysed alcoholysis of β-keto-esters and related compounds
- 1 January 1971
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society D: Chemical Communications
- No. 7,p. 355-356
- https://doi.org/10.1039/c29710000355
Abstract
Uncatalysed alcoholysis of alkyl acetoacetates and malonates occurs via a unimolecular dissociative mechanism involving concerted elimination of alcohol with resultant formation of substituted ketens as reactive intermediates.Keywords
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