Magnetic Resonance Analogies in Multidimensional Vibrational Spectroscopy

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Abstract
We survey the principles for the design of multidimensional vibrational spectroscopies that draw upon the analogy with liquid or solid state NMR and EPR spectroscopy. The much faster time-scales and the different energy regime in laser spectroscopy provide additional possibilities that lack magnetic spectroscopy counterparts. We also discuss the notion of through-bond vs through-space couplings between localized vibrations, which are of different nature than in NMR.